dc.contributor.author | ELJO, JASMIN | |
dc.contributor.author | Murphy, Graham K. | |
dc.date.accessioned | 2018-07-24 14:02:33 (GMT) | |
dc.date.available | 2018-07-24 14:02:33 (GMT) | |
dc.date.issued | 2018-08 | |
dc.identifier.issn | 0040-4039 | |
dc.identifier.uri | http://hdl.handle.net/10012/13489 | |
dc.identifier.uri | https://doi.org/10.1016/j.tetlet.2018.06.044 | |
dc.description.abstract | The oxidative halogenation of diaryl- or dialkylphosphine oxides with the hypervalent iodine reagents (difluoroiodo)toluene (p-TolIF2, 1) and (dichloroiodo)benzene (PhICl2, 2) is reported. Phosphoric fluorides could be recovered in 32–75% yield, or they could be trapped with EtOH to give the corresponding phosphinate in typically good yield. Phosphoric chlorides were not readily isolable, and were trapped with alcohol and amine nucleophiles, giving diaryl- or dialkylphos-phinates and phosphinamides in up to 90% yield. | en |
dc.description.sponsorship | Natural Sciences and Engineering Research Council
University of Waterloo
Province of Ontario | en |
dc.language.iso | en | en |
dc.publisher | Elsevier | en |
dc.rights | This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | en |
dc.subject | phosphoric chloride | en |
dc.subject | phosphoric fluoride | en |
dc.subject | hypervalent iodine | en |
dc.subject | phosphinate | en |
dc.subject | phosphinamide | en |
dc.title | Direct, oxidative halogenation of diaryl- or dialkylphosphine oxides with (dihaloiodo)arenes | en |
dc.type | Article | en |
dcterms.bibliographicCitation | Eljo, J., & Murphy, G. K. (2018). Direct, oxidative halogenation of diaryl- or dialkylphosphine oxides with (dihaloiodo)arenes. Tetrahedron Letters, 59(31), 2965–2969. https://doi.org/10.1016/j.tetlet.2018.06.044 | en |
uws.contributor.affiliation1 | Faculty of Science | en |
uws.contributor.affiliation2 | Chemistry | en |
uws.typeOfResource | Text | en |
uws.peerReviewStatus | Reviewed | en |
uws.scholarLevel | Faculty | en |
uws.scholarLevel | Graduate | en |