Direct, oxidative halogenation of diaryl- or dialkylphosphine oxides with (dihaloiodo)arenes

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dc.contributor.authorELJO, JASMIN
dc.contributor.authorMurphy, Graham K.
dc.date.accessioned2018-07-24T14:02:33Z
dc.date.available2018-07-24T14:02:33Z
dc.date.issued2018-08
dc.description.abstractThe oxidative halogenation of diaryl- or dialkylphosphine oxides with the hypervalent iodine reagents (difluoroiodo)toluene (p-TolIF2, 1) and (dichloroiodo)benzene (PhICl2, 2) is reported. Phosphoric fluorides could be recovered in 32–75% yield, or they could be trapped with EtOH to give the corresponding phosphinate in typically good yield. Phosphoric chlorides were not readily isolable, and were trapped with alcohol and amine nucleophiles, giving diaryl- or dialkylphos-phinates and phosphinamides in up to 90% yield.en
dc.description.sponsorshipNatural Sciences and Engineering Research Council University of Waterloo Province of Ontarioen
dc.identifier.issn0040-4039
dc.identifier.urihttp://hdl.handle.net/10012/13489
dc.identifier.urihttps://doi.org/10.1016/j.tetlet.2018.06.044
dc.language.isoenen
dc.publisherElsevieren
dc.rightsThis manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.subjectphosphoric chlorideen
dc.subjectphosphoric fluorideen
dc.subjecthypervalent iodineen
dc.subjectphosphinateen
dc.subjectphosphinamideen
dc.titleDirect, oxidative halogenation of diaryl- or dialkylphosphine oxides with (dihaloiodo)arenesen
dc.typeArticleen
dcterms.bibliographicCitationEljo, J., & Murphy, G. K. (2018). Direct, oxidative halogenation of diaryl- or dialkylphosphine oxides with (dihaloiodo)arenes. Tetrahedron Letters, 59(31), 2965–2969. https://doi.org/10.1016/j.tetlet.2018.06.044en
uws.contributor.affiliation1Faculty of Scienceen
uws.contributor.affiliation2Chemistryen
uws.peerReviewStatusRevieweden
uws.scholarLevelFacultyen
uws.scholarLevelGraduateen
uws.typeOfResourceTexten

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