Communication: Molecular-level insights into asymmetric triblock copolymers: Network and phase development

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dc.contributor.authorTallury, Syamal S.
dc.contributor.authorMineart, Kenneth P.
dc.contributor.authorWoloszczuk, Sebastian
dc.contributor.authorWilliams, David N.
dc.contributor.authorThompson, Russell B.
dc.contributor.authorPasquinelli, Melissa A.
dc.contributor.authorBanaszak, Michal
dc.contributor.authorSpontak, Richard J.
dc.date.accessioned2016-03-08T19:45:45Z
dc.date.available2016-03-08T19:45:45Z
dc.date.issued2014-10-01
dc.descriptionCopyright (2014) AIP Publishing. This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. The following article appeared in Journal of Chemical Physics (Communication) 141 and may be found at http://dx.doi.org/10.1063/1.4896612en
dc.description.abstractMolecularly asymmetric triblock copolymers progressively grown from a parent diblock copolymer can be used to elucidate the phase and property transformation from diblock to network-forming triblock copolymer. In this study, we use several theoretical formalisms and simulation methods to examine the molecular-level characteristics accompanying this transformation, and show that reported macroscopic-level transitions correspond to the onset of an equilibrium network. Midblock conformational fractions and copolymer morphologies are provided as functions of copolymer composition and temperature.en
dc.description.sponsorshipNonwovens Institute at North Carolina State University and the Polish Ministry of Science and Higher Education (Grant No. N204 125039).en
dc.identifier.urihttp://dx.doi.org/10.1063/1.4896612
dc.identifier.urihttp://hdl.handle.net/10012/10310
dc.language.isoenen
dc.publisherAIP publishingen
dc.relation.ispartofseriesJournal of Chemical Physics;141en
dc.subjectblock copolymersen
dc.subjectself-consistent field theoryen
dc.subjectcopolymersen
dc.titleCommunication: Molecular-level insights into asymmetric triblock copolymers: Network and phase developmenten
dc.typeArticleen
dcterms.bibliographicCitationTallury Syamal S., Mineart Kenneth P., Woloszczuk Sebastian, Williams David N., Thompson Russell B., Pasquinelli Melissa A., Banaszak Michal, Spontak Richard J. (2014). "Communication: Molecular-level insights into asymmetric triblock copolymers: Network and phase development", Journal of Chemical Physics, 144. doi: 10.1063/1.4896612en
uws.contributor.affiliation1Faculty of Scienceen
uws.contributor.affiliation2Physics and Astronomyen
uws.peerReviewStatusRevieweden
uws.scholarLevelFacultyen
uws.typeOfResourceTexten

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