Chemistry
This is the collection for the University of Waterloo's Department of Chemistry .
Research outputs are organized by type (eg. Master Thesis, Article, Conference Paper).
Waterloo faculty, students, and staff can contact us or visit the UWSpace guide to learn more about depositing their research.
Recent deposits
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Detection of Nitroaromatic Compounds through Fluorescence Quenching of Pyrene Labeled Starch Nanoparticles
(University of Waterloo, 2018-12-10)The aim of this research was to demonstrate the potential application of starch nanoparticles (SNPs) labeled with 1-pyrenebutyric acid (PBA) as the active component in optical sensors used for the detection of minute ... -
Development and validation of eco-friendly strategies based on thin film microextraction for water analysis
(Elsevier, 2018-12-07)The aim of the current study is the establishment of Green Analytical Chemistry strategies for water analysis by elimination/reduction of hazardous chemicals, energy consumption, and waste generation throughout the entire ... -
Exploiting the tunable selectivity features of polymeric ionic liquid-based SPME sorbents in food analysis
(Elsevier, 2018-10-01)In this work, the performances of polymeric ionic liquid (PIL) based solid-phase microextraction (SPME) coatings were assessed for applications concerning food safety and quality. Two different polymeric ionic liquid ... -
Direct immersion solid-phase microextraction analysis of multi-class contaminants in edible seaweeds by gas chromatography-mass spectrometry
(Elsevier, 2018-11-15)The present work aimed at the development of a simple and accurate direct immersion-solidphase microextraction-gas-chromatography-mass spectrometry (DI-SPME-GC-MS) method for simultaneous determination of PAHs, PCBs, and ... -
Synthesis of carboxylated derivatives of poly(isobutylene-co-isoprene) by azide–alkyne “click” chemistry
(Springer, 2018-09-28)The synthesis of carboxylated derivatives of poly(isobutylene-co-isoprene) (isobutylene–isoprene rubber, IIR) with substitution levels ranging from 1 to 4 mol% and different spacer lengths was accomplished through azide–alkyne ... -
The Synthesis of 3-Vinylindolines by the Palladium-Catalyzed Intramolecular Allylic Alkylation of Cinnamyl Acetates and the Synthesis of Polyphenolic 4-Aryl-3,4-dihydrocoumarins by Domino Friedel-Crafts Reactions
(University of Waterloo, 2018-10-24)Historically, the alkylation of allylic acetates with non-stabilized C(sp3) nucleophiles has been challenging. The metal-catalyzed alkylation of allylic acetates and carbonates with organotin and organoboron reagents has ... -
Effect of N-Oxide Incorporation on Thiazole-Containing Conjugated Polymers
(University of Waterloo, 2018-10-24)The use of conjugated polymers (CPs) in organic electronics has been an area of continued interest over the last several years due to many advantages over their inorganic counterparts. Due to the nature of CPs, devices can ... -
Magnetic nano-nets for capture of microbes in solution based on physical contact
(Elsevier, 2019-02-01)Self-assembly of Au nanoparticles with Fe ions is used to develop magnetic nano-nets similar to fishing nets for capture and removal of microbes in aqueous medium. The nano-nets have a high aspect ratio, span microns in ... -
Ultrasonic assisted synthesis, crystallographic, spectroscopic studies and biological activity of three new Zn(II), Co(II) and Ni(II) thiosemicarbazone complexes as precursors for nano-metal oxides
(Elsevier, 2019-01-01)Using ultrasonic irradiations, three new complexes of type [ZnL2].CH3CN, [NiLCl] and [CoL2] (where L is 2-acetylpyridine-4N-p-chlorophenylthiosemicarbazone ligand) have been prepared and investigated using various spectroscopic ... -
Mechanistic studies on the effect of membrane lipid acyl chain composition on daptomycin pore formation
(Elsevier, 2018-11-01)Daptomycin is a lipopeptide antibiotic that binds and permeabilizes the cell membranes of Gram-positive bacteria. Membrane permeabilization requires both calcium and phosphatidylglycerol (PG) in the target membrane, and ... -
Using Pyrene Excimer Fluorescence To Probe Polymer Diffusion in Latex Films
(American Chemical Society, 2017-02-28)This study introduces a simple technique that can be used to quantitatively probe interparticle polymer diffusion (IPD) between adjacent particles in a latex film using pyrene excimer fluorescence (PEF). To demonstrate the ... -
Conformation of Pyrene-Labeled Amylose in DMSO Characterized with the Fluorescence Blob Model
(American Chemical Society, 2016-10-25)Amylose and poly(methyl acrylate) were randomly labeled with pyrene to yield a series of Py-Amylose and Py-PMA constructs, and their ability to form excimer in DMSO was characterized quantitatively by steady-state and ... -
Using Pyrene Excimer Fluorescence To Probe the Interactions between Viscosity Index Improvers and Waxes Present in Automotive Oil
(American Chemical Society, 2017-03-28)A new methodology based on pyrene excimer fluorescence (PEF) was applied to quantitatively measure the actual level of intermolecular association between ethylene propylene (EP) copolymers in toluene in the presence of ... -
Long-Range, Polymer Chain Dynamics of a "Stiff" Polymer. Fluorescence from Poly(isobutylene-alt-maleic anhydride) with N-(1-Pyrenylmethyl)succinimide Groups
(American Chemical Society, 2017-04-25)The steady-state fluorescence (SSF) spectra and time resolved fluorescence (TRF) decays of five poly(isobutylene-alt-maleic anhydride) copolymers (PIMA), randomly labeled with N-(1-pyrenyl methyl)succinimide groups (Py-PIMA), ... -
Characterization of the Distribution of Pyrene Molecules in Confined Geometries with the Model Free Analysis
(American Chemical Society, 2017-12-21)Evidence is provided showing that global Model Free Analysis (MFA) of monomer and excimer fluorescence decays of pyrene dissolved in aqueous solutions of sodium dodecyl sulfate (SDS) provides the same structural and dynamic ... -
Path integral ground state approaches for the study of weakly bound clusters and confined molecules
(University of Waterloo, 2018-09-21)This thesis presents the study of weakly bound clusters in the ground state (or the zero-temperature limit) using path integral molecular dynamics. Specifically, we look individually at the quantum properties of small ... -
Porous chitosan microspheres as microcarriers for 3D cell culture
(Elsevier, 2018-12-15)Highly porous chitosan microspheres (CSM) were prepared through emulsion-based thermally induced phase separation (TIPS) without using toxic crosslinkers and chemical porogenic agents other than ice. The CSM had an average ... -
Characterizing Humulone Content in Beer Using Differential Mobility Spectrometry
(University of Waterloo, 2018-09-19)Beer is a complex fermented beverage and several hundreds of components have been identified erenow. Hops are extremely important to beer’s organoleptic qualities, especially bitterness. Bitterness, a distinguishing component ... -
Nonamphiphilic Assembly of Metal Carbonyl Complexes: Chemical Structure, Kinetics, and Hydrophobic Effect
(University of Waterloo, 2018-08-30)Self-assembly is an effective approach for the synthesis of various nanostructures. Assembly of amphiphilic molecules has been well developed, which are mostly thermodynamic controlled. Although the importance of kinetics ... -
Development and optimization of coated blade spray - mass spectrometry for bioanalytical and clinical applications
(University of Waterloo, 2018-08-23)Bioanalysis is a sub-discipline of analytical chemistry that focuses on the identification and quantification of small and large molecules (e.g. metabolites and proteins) present in biological sample matrices (e.g. blood, ...
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