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SHORT CHIRAL SYNTHESES OF MORPHINAN AND RELATED SYSTEMS

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dc.contributor.authorGao, Jihong
dc.date.accessioned2008-02-20T16:32:11Z
dc.date.available2008-02-20T16:32:11Z
dc.date.issued2008-02-20T16:32:11Z
dc.date.submitted2008
dc.description.abstractMorphine and its derivatives continue to challenge the creativity of synthetic chemists. The aim of this research is to execute a short chiral synthesis of the morphinan system. Chirality is introduced via asymmetric reduction; the key step is the formation of four rings- the tetracyclic phenanthrofuran by an intramolecular Diels-Alder cycloaddition. The fifth ring was completed by three different methods, and three different pentahydrophenanthrofuran systems were obtained.en
dc.identifier.urihttp://hdl.handle.net/10012/3586
dc.language.isoenen
dc.pendingfalseen
dc.publisherUniversity of Waterlooen
dc.subjectorganic synthesesen
dc.subjectmorphinan systemen
dc.subject.programChemistryen
dc.titleSHORT CHIRAL SYNTHESES OF MORPHINAN AND RELATED SYSTEMSen
dc.typeMaster Thesisen
uws-etd.degreeMaster of Scienceen
uws-etd.degree.departmentChemistryen
uws.peerReviewStatusUnrevieweden
uws.scholarLevelGraduateen
uws.typeOfResourceTexten

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