Nanostructured Carbons and Additives for Improvement of the Lithium-Sulfur Battery Positive Electrode

dc.comment.hiddenThe thesis includes work that has been published but the publishers do not require written permission. I have included the appropriate references in the thesis.en
dc.contributor.authorEvers, Scott Randall
dc.date.accessioned2013-04-19T20:44:43Z
dc.date.available2013-04-19T20:44:43Z
dc.date.issued2013-04-19T20:44:43Z
dc.date.submitted2013
dc.description.abstractLarge specific gravimetric/volumetric energy density, environmental benignity and safe low working voltage. All of these points have been used to describe the lithium sulfur (Li-S) battery in the past, but often times it is short cycle life and poor capacity retention that is associated with the Li-S battery. In order to realize the full potential of the Li-S battery in society today, many obstacles must be overcome. In a typical Li-S cell with an organic liquid electrolyte sulfur is reduced by lithium during discharge and subsequent lithium polysulfide species (Li2Sx where x, 2 < x < 8) are formed. These species are readily soluble in typical organic electrolytes and can lead to low Coulombic efficiency and most challenging: active mass loss. Through the loss of active mass, rapid capacity fading occurs over long-term cell cycling. Overcoming the loss of active mass and stabilizing cell capacity at high rates is pivotal to the realization of practical Li-S cells. In this thesis, four separate concepts and materials were studied and prepared with the aim to improve the Li-S batteries capacity, cycle life and capacity retention.en
dc.identifier.urihttp://hdl.handle.net/10012/7408
dc.language.isoenen
dc.pendingfalseen
dc.publisherUniversity of Waterlooen
dc.subjectLithium Sulfuren
dc.subjectBatteryen
dc.subject.programChemistryen
dc.titleNanostructured Carbons and Additives for Improvement of the Lithium-Sulfur Battery Positive Electrodeen
dc.typeMaster Thesisen
uws-etd.degreeMaster of Scienceen
uws-etd.degree.departmentChemistryen
uws.peerReviewStatusUnrevieweden
uws.scholarLevelGraduateen
uws.typeOfResourceTexten

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