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Dielectric Measurement and Analysis of Ultrastable PMMA Glass

dc.contributor.authorCai, Zhaohui
dc.date.accessioned2022-02-09T18:44:37Z
dc.date.available2022-02-09T18:44:37Z
dc.date.issued2022-02-09
dc.date.submitted2022-02-03
dc.description.abstractA stable glass, distinguished from an ordinary glass, has phenomenal characteristics such as a high density and a high kinetic stability. In this project, stable glasses of poly(methyl methacrylate) (PMMA) are produced by physical vapor deposition (PVD), and the dielectric responses of the vapor-deposited PMMA glasses are measured at 1 kHz with a high precision capacitance bridge. Measurements of the dielectric loss and storage have been done by heating and cooling the vapor-deposited PMMA glasses, where the heating and cooling cycles are used to rejuvenate the vapor-deposited PMMA glasses and to directly compare stable and nominally rejuvenated glasses. A noticeable suppression in β relaxation peak could be observed in the dielectric loss curve for vapor-deposited glasses (stable glasses) as compared to that for rejuvenated glasses (ordinary glasses). This finding implies that the glass stability essentially influences the dielectric relaxation.en
dc.identifier.urihttp://hdl.handle.net/10012/18066
dc.language.isoenen
dc.pendingfalse
dc.publisherUniversity of Waterlooen
dc.titleDielectric Measurement and Analysis of Ultrastable PMMA Glassen
dc.typeMaster Thesisen
uws-etd.degreeMaster of Scienceen
uws-etd.degree.departmentPhysics and Astronomyen
uws-etd.degree.disciplinePhysics (Nanotechnology)en
uws-etd.degree.grantorUniversity of Waterlooen
uws-etd.embargo.terms0en
uws.contributor.advisorForrest, James
uws.contributor.affiliation1Faculty of Scienceen
uws.peerReviewStatusUnrevieweden
uws.published.cityWaterlooen
uws.published.countryCanadaen
uws.published.provinceOntarioen
uws.scholarLevelGraduateen
uws.typeOfResourceTexten

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