Influence of Absorbency and Additives on Performance of Battery-Free IoT Water Leak Sensors

Abstract

Leak detection is a reliable solution for controlling the potentially destructive outflow and wastage of water. Several types of devices are used in domestic and industrial spaces; however, most have their power sources run out, and thus require battery change. The associated costs add to overhead expenditure of the user. This necessitates the use of leak detectors that are self-powered, having no use for external sources of power.

Integrating water leak detection systems with Internet of Things (IoT) technology such as Bluetooth low energy (BLE) and long-range (LoRa) protocols provides advantages such as real-time monitoring, which informs incidents and ultimately saves huge cost. The use of IoT-enabled sensors and cloud-based data analytics offers pre-emptive control mechanisms for prompt identification and containment of localized leaks. This helps reduce wastage of water and damage to property, both of which reduce costs as remote access through IoT networks guarantee instant notifications for preventative measures. Scalability fosters effortless deployment in residential, commercial, and industrial environments.

In a self-powered IoT water leak device, parameters such as capillary action and electrochemical reactions directly impact power generation and beacon activation. Energy generation and harvesting happen as water interacts with active materials within the sensor device. There must be a cathode and an anode, to interact with the leaking water which would be the electrolyte. Therefore, the materials selected to play such roles in the device are crucial for the desirable chemical interactions, once in contact with the leaking water.

In a water leak detector where the most crucial feature is sensitivity to water, capillary action is one of the most significant parameters to consider. Both the design of the sensor casing and channels through which the water travels, are to foster a seamless flow. Also, within the sensor chamber, each material in the stack must demonstrate capillarity. Therefore, porosity is key, as their pore sizes determine what material passes through and what might otherwise be trapped to impede the flow of the water being transmitted. Therefore, capillary action is explored for absorbent materials and the sensor casing. Both filter paper (FP) and fabric materials are examined, to ascertain which one gives optimally combined advantages for absorbency and repeatability. FP showed superior performance, due to its pore size. This advantage becomes particularly useful where additives are considered for the powder mixture.

Without additives, the stacked materials have only water to interact with. While this is sufficient to power BLE, it is not enough for LoRa technologies which require higher power. To account for this, additives can be included in the materials within the sensor stack. Salts are among such additives that can provide active ions when interacting with water. Subsequently, these ions facilitate electricity generation due to increased current. Therefore, the power output of the device can be increased when additives are introduced. In previous similar works, it was shown that pure materials without any additives produce an open-circuit voltage (OCV) of 2 V and short-circuit current (SCC) of only 10 mA. This combination was able to power the sensor for beacon activation through 7 cycles of wetting-drying rounds of repeatability, but only for the BLE protocol. To solve for this limitation, NaCl was added in varied proportions. 10 wt.% NaCl was found to outperform other samples. After several rounds of repeatability, the values of current and voltage were observed to diminish. A sensor without NaCl typically lasts 7 rounds of repeatability, sensors containing NaCl last only about 3 rounds. The primary concern with the use of such additives may be an imminent trade-off between the increased power generation and possible corrosion which compromises shelf life.

One of the downsides of using additives to enhance power generation is the corrosion of metallic materials in the sensor. To study the effect of NaCl on the corrosion of the metallic material, and thus the shelf life of the sensor, electrochemical corrosion tests were performed. As expected, it was observed that higher salt content resulted in higher corrosion rate. Therefore, repeatability was significantly reduced in higher salt contents, thereby limiting the overall shelf life of the sensor. Ultimately, the use of salts should be limited and be specific to the target use case.