Defect Investigation on Hematite Photoanodes

dc.contributor.authorLiu, Yutong
dc.date.accessioned2023-05-17T19:36:39Z
dc.date.available2023-09-15T04:50:06Z
dc.date.issued2023-05-17
dc.date.submitted2023-05-08
dc.description.abstractEfforts to improve the efficiency of photoelectrocatalytic reactions on hematite photoanodes routinely focus on the analysis of photophysics, or on the fabrication of complex material architectures. The discontinuity of experimental results and mechanistic proposals found across the literature, however, reflect a lack of control over detailed structural features. This thesis aims to analyze specific types of structural defects and correlate their presence to photoelectrocatalytic behavior parameters. Following this strategy, we successfully identify coexistent defects in hematite photoanodes. This finding provides a means to rapidly diagnose a specific structural defect with Raman spectroscopy and will aid in the optimization of fabrication protocols for hematite photoanodes.en
dc.identifier.urihttp://hdl.handle.net/10012/19458
dc.language.isoenen
dc.pendingfalse
dc.publisherUniversity of Waterlooen
dc.subjecthematiteen
dc.subjectphotoanodeen
dc.titleDefect Investigation on Hematite Photoanodesen
dc.typeDoctoral Thesisen
uws-etd.degreeDoctor of Philosophyen
uws-etd.degree.departmentChemistryen
uws-etd.degree.disciplineChemistryen
uws-etd.degree.grantorUniversity of Waterlooen
uws-etd.embargo.terms4 monthsen
uws.contributor.advisorSmith, Rodney
uws.contributor.affiliation1Faculty of Scienceen
uws.peerReviewStatusUnrevieweden
uws.published.cityWaterlooen
uws.published.countryCanadaen
uws.published.provinceOntarioen
uws.scholarLevelGraduateen
uws.typeOfResourceTexten

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