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Development and Performance Characterization of Bipolar Electrodialysis Flow Batteries

dc.contributor.authorCleland, Keith
dc.date.accessioned2022-12-22T14:13:46Z
dc.date.issued2022-12-22
dc.date.submitted2022-12-15
dc.description.abstractEnergy storage is becoming increasingly important to have a consistent renewable power supply. Limitations on the cost of current energy storage technologies have prevented the mass adoption of renewable energy. This research focusses on the development of a flow battery using low-cost electrolyte materials based on bipolar electrodialysis technology. The battery operates by splitting salt water via electricity in conjunction with a bipolar membrane and ion exchange membranes to make acidic and basic solutions. The acid and base can then be neutralized at the bipolar membrane, generating voltage and current that can be used as electricity. A bipolar electrodialysis flow battery was designed, constructed, and improved to provide reliable and repeatable operation. Bipolar membranes with different membrane chemistries and materials were tested at different temperatures to understand the losses associated with bipolar electrodialysis flow batteries. A protocol was developed with an analytical framework to compare the results of the polarization curves in a simple way, without the need for fit parameters. Through the measurement of the membrane resistance and a polarization curve, ohmic and overpotential related losses could be distinguished. Links between these losses and the physical phenomena that take place within the bipolar membrane were made. This research provides insight on how to tailor improvements to the bipolar membranes for more efficient flow batteries using cost effective, sustainable electrolytes.en
dc.identifier.urihttp://hdl.handle.net/10012/18988
dc.language.isoenen
dc.pendingfalse
dc.publisherUniversity of Waterlooen
dc.subjectflow batteryen
dc.subjectbipolar electrodialysisen
dc.subjectbipolar membraneen
dc.subjection exchange membraneen
dc.subjectenergy storageen
dc.titleDevelopment and Performance Characterization of Bipolar Electrodialysis Flow Batteriesen
dc.typeMaster Thesisen
uws-etd.degreeMaster of Applied Scienceen
uws-etd.degree.departmentChemical Engineeringen
uws-etd.degree.disciplineChemical Engineeringen
uws-etd.degree.grantorUniversity of Waterlooen
uws-etd.embargo2024-12-21T14:13:46Z
uws-etd.embargo.terms2 yearsen
uws.comment.hiddenNote: This thesis is confidential, and is not to be disclosed for a period of 5 years from the date of this submission, as per a sponsored research agreement with the University of Waterloo. Given the system has only provided an option for 2 years for the embargo, I can contact UWSpace to ensure that the thesis is not released to the public before the 2 year period is over.en
uws.contributor.advisorGostick, Jeff
uws.contributor.advisorBenneker, Anne
uws.contributor.affiliation1Faculty of Engineeringen
uws.peerReviewStatusUnrevieweden
uws.published.cityWaterlooen
uws.published.countryCanadaen
uws.published.provinceOntarioen
uws.scholarLevelGraduateen
uws.typeOfResourceTexten

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