Browsing Science (Faculty of) by Author "Little, Hunter"
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Calibrating the Long-Range Backbone Dynamics of Polymers in Solution Using Two Different Models
Little, Hunter (University of Waterloo, 2022-09-29)The fluorescence decays of a series of 41 pyrene-labeled poly(oligo(ethylene glycol)methyl ether methacrylate)s (Py-PEGnMA where n = 0, 1, 2, 3, 4, 5, 9, 16, 19) were prepared by free-radical polymerization of 1-pyrenebutyl ... -
Characterization of the Distribution of Pyrene Molecules in Confined Geometries with the Model Free Analysis
Cao, Xinzhi; Casier, Remi; Little, Hunter; Duhamel, Jean (American Chemical Society, 2017-12-21)Evidence is provided showing that global Model Free Analysis (MFA) of monomer and excimer fluorescence decays of pyrene dissolved in aqueous solutions of sodium dodecyl sulfate (SDS) provides the same structural and dynamic ... -
Hydrophobic and Elastic Forces Experienced by a Series of Pyrene End-Labeled Poly(ethylene oxide)s Interacting with Sodium Dodecyl Sulfate Micelles
Raimbault, Justin; Casier, Remi; Little, Hunter; Duhamel, Jean (American Chemical Society, 2018-07-30)A series of pyrene end-labeled poly(ethylene oxide)s (Py2-PEO(x) with x equal to 2, 3.4, 5, 6, 7.8, and 10 kg mol–1) were synthesized, and their interactions with SDS micelles were characterized by steady-state and ...