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Manufacturing of a Fiber-Reinforced Thermoplastic Composite Micro-Generating Wind Turbine Blade

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Date

2023-11-20

Authors

Zivkovic, Milos

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Publisher

University of Waterloo

Abstract

In response to climate legislation attempting to curb global greenhouse emissions, renewable energy technologies have seen rapidly increasing global demand over the past two decades, with significant attention paid to the wind energy sector. Large, MW-scale wind turbines routinely exceed 100-meters in blade length, enabling reliable clean energy to be accessed by urban communities. However, such structures are often not feasible in remote communities that are not connected to the electrical grid. In Northern Canada, these communities are often reliant on diesel generators for reliable energy despite their inefficiency and emission of harmful pollutants. Thus, the development of renewable energy solutions that can be applied to smaller communities – such as small-scale, micro-generating wind turbine blades that produce up-to 100 KW of power – are a timely engineering problem. Generally, high-performance blade structures take advantage of fiber-reinforced plastic (FRP) composite materials that allow for high strength-to-weight ratios and excellent fatigue performance. However, legacy turbine blade material systems suffer from poor end-of-life recyclability due to issues with recovering conventional thermosetting epoxy polymer resin systems that cannot be melted and reformed. Thus, the composites industry is rapidly transitioning to alternate plastic formulations that maximize performance while considering holistic product lifecycles. In-situ polymerizable thermoplastic resins represent one such alternative. These novel resin systems comprise monomers that polymerize in-situ during part production. The low flow viscosity of these resins enables their use with cost-effective processes such as vacuum assisted resin-transfer molding (VARTM). Unlike thermosetting polymers (such as epoxy) that undergo irreversible curing during processing, thermoplastic materials can be melted and reformed at sufficiently high temperatures, allowing for full reclamation of the composite material system at the conclusion of its service life. The goal of this thesis was to manufacture a full-scale micro-generating wind turbine blade comprising glass-fiber reinforced in-situ polymerizable thermoplastic resin shells using a VARTM process in a cost-effective manner. Three main objectives were identified to complete this project. The first objective was to optimize a baseline VARTM process to reliably produce flat panels with optimized fiber volume fraction (𝑉𝑓) and void volume fraction (𝑉𝑐). Second, a suitable adhesive joining system for the composite was to be identified, with Mode I double cantilever beam and Mode II end notched flexural tests performed at room and low temperatures to simulate the expected ambient conditions in remote Northern Canadian communities, with a consideration for bond-line thickness effects. Finally, the findings from the first two tasks were to be synthesized and adapted to enable the production of full-scale, high-quality micro-generating wind turbine blades by joining two separately produced shells. A process study was performed to minimize void formation during flat panel manufacturing stemming from transverse flow, dual-scale flow, and race-tracking, while maintaining sufficient compaction during polymerization. Microscopic analysis and visual inspection were used to measure fiber volume fraction and observe void formations. The optimized high-quality panels exhibited an average fiber volume fraction of 46.28 (±1.2)%. The removal of a polymeric veil from the unidirectional non-crimp fabric architecture contributed to an increase in fiber volume fraction of 8.2%. The observed fiber volume fractions with the optimized VARTM process are within 2.5% of literature results for E-glass UD-NCF composite panels produced with SCRIMP processes. Adhesive test results showed that the methyl methacrylate (MMA) adhesive experienced ductile cohesive failure at room temperature (RT; 23°C), and brittle failure within the adhesive and substrate at low temperature (LT; -40°C) depending on the load condition. RT DCB tests showed an increase of 45% in fracture energy in the adhesive joint with increasing bond-line thickness, while LT test specimens exhibited lower loads and an oscillatory crack tip propagation pattern implying accumulated residual stresses in the adhesive layer due to thermal expansion incompatibility with the composite substrate. ENF specimens showed a reduced load capability at LT conditions with a higher elastic stiffness and failure within the substrate. Fabrication of a full-scale proof-of-concept blade showed that accommodating fabric drapability was critical for a high-quality infusion, and that the material system can be successfully adapted for production pending revisions to the adhesive surface geometries. While the trailing edge of the blade allowed for a robust adhesive joint, the blade shell concavities along the leading edge meant that the shells mated along the thickness of the composite, creating a weak bond with significant cracks and porosities in the adhesive layer. Future trials should incorporate a representative fabric stacking sequence and modified joint geometries to compare the static deflection of the updated thermoplastic material system with legacy carbon fibre-reinforced epoxy composite blades.

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Keywords

thermoplastic, composite, vacuum infusion, methacrylate adhesive, glass fiber, adhesive characterization

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