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dc.contributor.authorTatarchuk, Stephen William
dc.date.accessioned2021-05-14 14:27:37 (GMT)
dc.date.available2021-05-14 14:27:37 (GMT)
dc.date.issued2021-05-14
dc.date.submitted2021-05-08
dc.identifier.urihttp://hdl.handle.net/10012/16985
dc.description.abstractElectrochemical oxidation of urea provides an approach to prevent excess urea emissions into the environment while generating value by capturing chemical energy from waste. Unfortunately, the source of high catalytic activity in state-of-the-art doped nickel catalysts for urea oxidation reaction (UOR) activity remains poorly understood, hindering the rational design of new catalyst materials. In particular, the exact role of cobalt as a dopant in Ni(OH)2 to maximize the intrinsic activity towards UOR remains unclear. This thesis explores how tuning the Ni:Co ratio in a modified propylene oxide synthesis of Ni1-xCox(OH)2 xerogel catalysts alters both structural and electronic states which allows one to tune the number and intrinsic activity of redox-active surface sites towards UOR. For the Ni1-xCox(OH)2 catalysts studied, Ni90Co10 (OH)2 achieves the largest geometric current density due to the increase of available surface sites and that intrinsic activity towards UOR is maximized with Ni20Co80(OH)2. Through density functional theory calculations, we show that the introduction of Co alters the Ni 3d electronic state density distribution to lower the minimum energy required to oxidize Ni and influence potential surface adsorbate interactions.en
dc.language.isoenen
dc.publisherUniversity of Waterlooen
dc.subjecturea oxidation reactionen
dc.subjectelectronic structureen
dc.subjectnickel-cobalt hydroxideen
dc.subjectelectrocatalysisen
dc.subjectDFTen
dc.subjectsol-gelen
dc.titleDevelopment of Cobalt-Doped Nickel Hydroxide Sol-Gel Catalysts for Enhanced Electro-Oxidation of Ureaen
dc.typeMaster Thesisen
dc.pendingfalse
uws-etd.degree.departmentChemistryen
uws-etd.degree.disciplineChemistryen
uws-etd.degree.grantorUniversity of Waterlooen
uws-etd.degreeMaster of Scienceen
uws-etd.embargo.terms0en
uws.contributor.advisorKlinkova, Anna
uws.contributor.affiliation1Faculty of Scienceen
uws.published.cityWaterlooen
uws.published.countryCanadaen
uws.published.provinceOntarioen
uws.typeOfResourceTexten
uws.peerReviewStatusUnrevieweden
uws.scholarLevelGraduateen


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