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dc.contributor.authorTolami Hemmati, Sahar
dc.contributor.authorLi, Ge
dc.contributor.authorWang, Xiaolei
dc.contributor.authorDing, Yuanli
dc.contributor.authorPei, Yu
dc.contributor.authorYu, Aiping
dc.contributor.authorChen, Zhongwei
dc.date.accessioned2019-01-04 16:06:37 (GMT)
dc.date.available2019-01-04 16:06:37 (GMT)
dc.date.issued2019-02
dc.identifier.urihttps://doi.org/10.1016/j.nanoen.2018.10.048
dc.identifier.urihttp://hdl.handle.net/10012/14302
dc.descriptionThe final publication is available at Elsevier via https://doi.org/10.1016/j.nanoen.2018.10.048. © 2018. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.description.abstractHerein, a unique nitrogen-doped T-Nb2O5/tubular carbon hybrid structure in which T-Nb2O5 nanoparticles are homogeneously embedded in an in-situ formed nitrogen-doped microtubular carbon is synthesized, utilizing a facile and innovative synthesis strategy. This structure addresses the poor electron conductivity and rate capability that hinder T-Nb2O5's promise as an anode for Li-ion devices. Such a distinctive structure possesses a robust framework that has ultrasmall active nanocomponents encapsulated in highly conductive carbon scaffold with hollow interior and abundant voids, enabling fast electron/ion transport and electrolyte penetration. Moreover, nitrogen-doping not only ameliorates the electronic conductivity of the heterostructure, but also induces pseudocapacitance mechanism. When evaluated in a half-cell, the as-prepared material delivers a specific capacitance of 370 F g−1 at 0.1 A g−1 within 1–3 V vs. Li/Li+ and excellent cyclability over 1100 cycles. A high energy density of 86.6 W h kg−1 and high power density of 6.09 kW kg−1 are realized. Additionally, a capacitance retention as high as 81% after 3500 cycles is achieved in an Li-ion Capacitor (LIC) with activated carbon as the cathode and nitrogen-doped T-Nb2O5/tubular carbon as the anode.en
dc.description.sponsorshipNatural Sciences and Engineering Research Council University of Waterlooen
dc.language.isoenen
dc.publisherElsevieren
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectLi-ion intercalation pseudocapacitanceen
dc.subjectorthorhombic niobium oxideen
dc.subjectin-situ polymerizationen
dc.subjectnitrogen dopingen
dc.title3D N-doped hybrid architectures assembled from 0D T-Nb2O5 embedded in carbon microtubes toward high-rate Li-ion capacitorsen
dc.typeArticleen
dcterms.bibliographicCitationThe final publication is available at Elsevier via https://doi.org/10.1016/j.nanoen.2018.10.048. © 2018. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/en
uws.contributor.affiliation1Faculty of Engineeringen
uws.contributor.affiliation2Chemical Engineeringen
uws.contributor.affiliation2Waterloo Institute for Nanotechnology (WIN)en
uws.contributor.affiliation2Waterloo Institute for Sustainable Energy (WISE)en
uws.typeOfResourceTexten
uws.peerReviewStatusRevieweden
uws.scholarLevelFacultyen
uws.scholarLevelPost-Doctorateen
uws.scholarLevelGraduateen


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