UWSpace is currently experiencing technical difficulties resulting from its recent migration to a new version of its software. These technical issues are not affecting the submission and browse features of the site. UWaterloo community members may continue submitting items to UWSpace. We apologize for the inconvenience, and are actively working to resolve these technical issues.
 

Stille Coupling of α-Acyloxybenzylstannanes with Acid Chlorides

Thumbnail Image

Files

Xu_Junhui.pdf (3.76 MB)

Date

2016-08-19

Authors

Xu, Junhui

Journal Title

Journal ISSN

Volume Title

Publisher

University of Waterloo

Abstract

Two widely-accepted models (open- and cyclic- transmetalation) are applied to explain the stereochemical outcome of the Stille coupling with organotin compounds containing an sp3 chiral center. However, it is still not possible to predict the stereochemical outcome of this type of Stille coupling before the reaction is conducted. To have a better understanding of the detailed mechanism involved, the Stille couplings of different α-acyloxybenzylstannanes with different acid chlorides were studied in this project.

Description

Keywords

Stille coupling

LC Keywords

Citation

URI

http://hdl.handle.net/10012/10662

Collections

Theses
Chemistry