Browsing Physics and Astronomy by Subject "nanocomposites"
Now showing items 1-7 of 7
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Block Copolymer-Directed Assembly of Nanoparticles: Forming Mesoscopically Ordered Hybrid Materials
(American Chemical Society, 2002)Mixtures of diblock copolymers and nanoscopic spherical particles can yield well-ordered hybrid materials, which can be used for separation processes, catalysis, and optoelectronic applications. Predicting the morphologies ... -
Effect of Nanoscopic Particles on the Mesophase Structure of Diblock Copolymers
(American Chemical Society, 2002)Introduction. The fabrication of novel biomimetic photonic and electronic materials requires the manipulation of both organic and inorganic materials at the nanometer length scale. One possible means of achieving this level ... -
Entropically Driven Formation of Hierarchically Ordered Nanocomposites
(American Physical Society, 2002)Using theoretical models, we undertake the first investigation into the rich behavior that emerges when binary particle mixtures are blended with microphase-separating copolymers. We isolate an example of coupled self-assembly ... -
Particle Distributions in a Block Copolymer Nanocomposite
(American Chemical Society, 2008)Self-consistent-field theory is used to predict the center-of-mass distribution of spherical nanoparticles embedded in the lamellar phase of a diblock copolymer melt. The calculation is performed in the dilute limit, where ... -
Predicting the Mesophases of Copolymer-Nanoparticle Composites
(American Association for the Advancement of Science, 2001)The interactions between mesophase-forming copolymers and nanoscopic par- ticles can lead to highly organized hybrid materials. The morphology of such composites depends not only on the characteristics of the copolymers, ... -
Self-assembly of a binary mixture of particles and diblock copolymers
(Royal Society of Chemistry, 2003)Using theoretical models, we undertake the first investigation into the synergy and rich phase behavior that emerges when binary particle mixtures are blended with microphase- separating copolymers. We isolate an example ... -
Self-Assembly of Amphiphilic Nanoparticle-Coil “Tadpole” Macromolecules
(American Chemical Society, 2004)There has been considerable fascination with the self-assembling behavior of amphiphilic chainlike molecules that range from short-chain surfactants to high molecular weight block copolymers. The self-assembly of simple ...