Application of Nanomaterials for X-ray Shielding and Dosimetry in Diagnostic Radiology
MetadataShow full item record
Lead is commonly used in medical radiology departments as a shielding material against X-rays. Lead-based protective materials are also routinely used by clinical personnel and patients during radiological examinations or procedures. However, lead is extremely toxic and prolonged exposure to it can result in serious health concerns. In this thesis, a novel, lead-free, cost-effective nanocomposite was developed for X-ray protection applications. Conformable polymer nanocomposites from polydimethylsiloxane (PDMS) were fabricated using different weight percentages (wt%) of bismuth oxide (BO) nanopowder. BO has a relatively high atomic-number which allowed increased X-ray interactions required for the X-ray photons to deposit energy within the PDMS/BO nanocomposite. The attenuation properties of the nanocomposites were characterized using diagnostic X-ray energies from 40 to 150 kV. The results showed that the PDMS/BO nanocomposite (44.44 wt% of BO and 3.73 mm thick) was capable of attenuating all the scattered X-rays generated at a tube potential of 60 kV. Another aspect of my thesis-work involves X-ray detection using bismuth sulfide (Bi2S3) nanoflowers and organic polymer nanocomposite. There is an increasing demand for real-time, large-area, flexible dosimeters, especially in the biomedical industry. In this thesis, photoelectric response of hydrothermally synthesized Bi2S3 nanoflowers was measured under both low X-ray energies (20 to 30 kV), and higher diagnostic X-ray energies (40 to 100 kV). The photoresponse of the nanoflowers clearly showed high sensitivity to changes in X-ray intensities, the capability to operate at relatively low bias voltages (+1 and +1.5 V under X-rays in the mammographic and higher diagnostic energies respectively), and the potential to perform as a reliable dosimetric material for instantaneous dose measurements over a wide range of diagnostic X-rays. Finally, the nanoflowers were incorporated into a p-type, semiconducting organic polymer (P3HT). The photoelectric response of the both pure P3HT and P3HT/Bi2S3-nanocomposite devices was measured under X-rays in the diagnostic energy range. The P3HT/Bi2S3-nanoflower composite showed significantly higher sensitivity (~4 times under 100 kV X-rays) compared to that of pure polymer. In summary, the flexible P3HT/Bi2S3-nanoflower device could potentially be used over an uneven surface for real-time detection of diagnostic X-rays at a minimal operating voltage of -40 mV.
Cite this work
Shruti Nambiar (2015). Application of Nanomaterials for X-ray Shielding and Dosimetry in Diagnostic Radiology. UWSpace. http://hdl.handle.net/10012/9375
Showing items related by title, author, creator and subject.
Spinel Oxides and Heteroatom-doped Carbon Nano-composite as Bi-functional Oxygen Electrocatalyst for Rechargeable Zinc-Air Battery Park, Moon Gyu (University of Waterloo, 2015-08-27)With continued increase in energy demand for high energy-required devices such as portable electronics and electric vehicles, development of innovative energy conversion and storage systems has attracted tremendous attention. ...
Wu, Huikang (University of Waterloo, 1997)
Shin, Sang Young (University of Waterloo, 2008-01-22)Abstract Chapter 1 provides an overview of this study and a literature review. Emphasis is put on the materials used, the different processes available to synthesize polymer-clay nanocomposites, analytical methods to ...