Tallury, Syamal S.Mineart, Kenneth P.Woloszczuk, SebastianWilliams, David N.Thompson, Russell B.Pasquinelli, Melissa A.Banaszak, MichalSpontak, Richard J.2016-03-082016-03-082014-10-01http://dx.doi.org/10.1063/1.4896612http://hdl.handle.net/10012/10310Copyright (2014) AIP Publishing. This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. The following article appeared in Journal of Chemical Physics (Communication) 141 and may be found at http://dx.doi.org/10.1063/1.4896612Molecularly asymmetric triblock copolymers progressively grown from a parent diblock copolymer can be used to elucidate the phase and property transformation from diblock to network-forming triblock copolymer. In this study, we use several theoretical formalisms and simulation methods to examine the molecular-level characteristics accompanying this transformation, and show that reported macroscopic-level transitions correspond to the onset of an equilibrium network. Midblock conformational fractions and copolymer morphologies are provided as functions of copolymer composition and temperature.enblock copolymersself-consistent field theorycopolymersArticle