Browsing Science (Faculty of) by Supervisor "Fillion, Eric"
Now showing items 1-3 of 3
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Methodology Development for the Electrophilic Aromatic Amination of Secondary Amides
(University of Waterloo, 2022-01-25)The intramolecular electrophilic aromatic amination of secondary amides was developed. Secondary N-methoxy and N-p-methoxyphenyl amides were cyclized to oxindoles by triflic anhydride mediated electrophilic activation and ... -
The Synthesis of 3-Vinylindolines by the Palladium-Catalyzed Intramolecular Allylic Alkylation of Cinnamyl Acetates and the Synthesis of Polyphenolic 4-Aryl-3,4-dihydrocoumarins by Domino Friedel-Crafts Reactions
(University of Waterloo, 2018-10-24)Historically, the alkylation of allylic acetates with non-stabilized C(sp3) nucleophiles has been challenging. The metal-catalyzed alkylation of allylic acetates and carbonates with organotin and organoboron reagents has ... -
Synthesis, Characterization, and Reactivity of Tricarbastannatranes
(University of Waterloo, 2016-06-16)The synthesis of a series of tricarbastannatrane complexes is described, and the structure of ionic triptych complexes [N(CH2CH2CH2)3Sn](BF4), [N(CH2CH2CH2)3Sn](SbF6), [N(CH2CH2CH2)3Sn]4[(SbF6)3Cl], [(N(CH2CH2CH2)3Sn)2OH ...